1) Why are Voltmeters placed in parallel whereas ammeters placed in series.
It is worth noting that the structures of ammeters and voltmeters are identical. Volmeters just have a resistor connected in series within them.
So if a voltmeter is connected in series in a circuit then not much current would pass it, and so devices (eg. light globe) on the circuit would not be able to be powered. So it is connected in in parallel.
Ammeters on the other hand do not have much resistance, so if you connect them in parallel then alot of current will flow (current flows in the path with least resistance), and not through the load/device. So they need to be connected in series to measure the current being supplied to the load/device.
A good analogy is a water circuit. Consider the pump to be the source and a resistor be anything that obstructs the flow of water (eg. a narrower pipe than the rest of the circuit). A voltmeter would measure the pressure 'difference' in pressure on either side of the 'resistor' and the ammeter would measure how much water (analogous to current) flowing.
2) Why are AC used in homes instead of DC.
DC voltages are difficult to step up and step down, whereas AC is easier to step up and step down (using transformers). Also, it is easier to convert AC in DC, than DC into AC, which is required for household specific household appliances.
Power loss = I^2 * R, so we need to reduce I to reduce power loss.
Now P=IV, so if we are going to decrease I, we need to increase V if we're going to maintain the same amount of power being transmitted. This is done by stepping up voltages. Hence why AC is used.
But if DC could be transformed easily then it could well be a better way to transmit electricity for various reasons that you will study in Year 12 HSC Physics.