For ii), why isn't it 1/3 x 2/3 x 3/3?
If James has to search all three levels before finding his car, then it has to be on the last level he searches. At first, there are three levels he can choose from to search. Two of the levels don't have his car, so there is a 2/3 chance that James will search a level that does not have his car. Once he has searched that level, there are two remaining levels, one of which has his car. There is a 1/2 chance that James will pick the wrong level to search. Finally, there is only level for James to search, and since this level has his car, the chance of him finding it there is 1.
For (iii), there is a 1/3 chance that James will pick the correct level straight away. We want the complementary event of this, which is James picking the incorrect level initially. This event has a 2/3 chance of happening. Since the question asks for the chance of this happening for 5 days we multiply the probabilities, calculating 2/3 * 2/3 * 2/3 * 2/3 * 2/3, or (2/3)^5.