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AAS question help (1 Viewer)

hungreypotter

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i dont really understand how to do this question so could someone explain. i looked at the sample answer but i don't get what they are trying to convey, the working out is kinda unclear.
thanks so much!
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Luukas.2

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The solution is 12.5 ppm in Cu2+ ions but the solid formed is CuCO3.

The question is also implying that all of the copper can be precipitated as CuCO3, which isn't true because there will be a solubility equilibrium, but almost all of it can be precipitated if enough carbonate is added without increasing the volume too much, and if Ksp(CuCO3) is small.
 

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