• Congratulations to the Class of 2024 on your results!
    Let us know how you went here
    Got a question about your uni preferences? Ask us here

Chemistry Marathon (HSC) (1 Viewer)

deswa1

Well-Known Member
Joined
Jul 12, 2011
Messages
2,256
Gender
Male
HSC
2012
This is for people doing industrial chem- I won't post any more optional questions because not everyone can do them obviously but this one is fantastic and deserves to posted:

The ionisation of acetic acid can be written as CH3COOH -> <- CH3COO (-) + H (+). The equilibrium constant for this reaction is 1.8x10^-5. A 0.5mol/L solution of acetic acid is made up. Calculate the pH of the resultant solution at equilbrium.
 

barbernator

Active Member
Joined
Sep 13, 2010
Messages
1,439
Gender
Male
HSC
2012
This is for people doing industrial chem- I won't post any more optional questions because not everyone can do them obviously but this one is fantastic and deserves to posted:

The ionisation of acetic acid can be written as CH3COOH -> <- CH3COO (-) + H (+). The equilibrium constant for this reaction is 1.8x10^-5. A 0.5mol/L solution of acetic acid is made up. Calculate the pH of the resultant solution at equilbrium.
pH = 12.7 ??
 

Sanjeet

Member
Joined
Apr 20, 2011
Messages
239
Gender
Male
HSC
2012
This is for people doing industrial chem- I won't post any more optional questions because not everyone can do them obviously but this one is fantastic and deserves to posted:

The ionisation of acetic acid can be written as CH3COOH -> <- CH3COO (-) + H (+). The equilibrium constant for this reaction is 1.8x10^-5. A 0.5mol/L solution of acetic acid is made up. Calculate the pH of the resultant solution at equilbrium.
Anyone have a solution?
 

barbernator

Active Member
Joined
Sep 13, 2010
Messages
1,439
Gender
Male
HSC
2012
Anyone have a solution?
1. Write out the equilibrium expression
2. We want to replace everything that is not [H+] with either [H+] or a constant
3. We know from standard ionisation that [H+] = [CH3COO-]
4. as 0.5 mol/L of Acetic acid is originally placed in the beaker, and these molecules either stay in their molecular form or ionise, we can say that [H+] + [CH3COOH] = 0.5
5. Replace all things other than [H+]
6. Solve quadratic taking the positive solution
7. Use pH = -log[H+]
8. Presto!
 
Last edited:

someth1ng

Retired Nov '14
Joined
Sep 18, 2010
Messages
5,558
Location
Adelaide, Australia
Gender
Male
HSC
2012
Uni Grad
2021
1. Write out the equilibrium expression
2. We want to replace everything that is not [H+] with either [H+] or a constant
3. We know from standard ionisation that [H+] = [CH3COO-]
4. as 0.5 mol/L of Acetic acid is originally placed in the beaker, and these molecules either stay in their molecular form or ionise, we can say that [H+] + [CH3COOH] = 0.5
5. Replace all things other than [H+]
6. Solve quadratic taking the positive solution
7. Use pH = -log[H+]
8. Presto!
lol...fuck that - won't be in the exam :p
 

madharris

Well-Known Member
Joined
Oct 23, 2011
Messages
2,160
Gender
Undisclosed
HSC
N/A
Is industrial chem good?
Shipwrecks is so boring imo
 

cerebellum

Member
Joined
Jul 16, 2012
Messages
54
Gender
Female
HSC
2012
I also got pH = 2.52 (3 sig figs).
What else you got, bring it.
:)
 

madharris

Well-Known Member
Joined
Oct 23, 2011
Messages
2,160
Gender
Undisclosed
HSC
N/A
A student said that the use of ethanol as a fuel is entirely carbon neutral. Evaluate this statement with appropriate equations
Not sure how many marks but oh well, I'll try :)

Ethanol is a renewable resource which can be made from cellulose. Cellulose is a naturally occuring condensation polymer which makes up about 50% of the earths biomassIt is manufactured by photosynthesis in plants, fermentation then combustion in vehicles. THis means that it's 'carbon neutral':
photosynthesis: 6CO2(g) + 6H2(l)L --> 6O2(g) + C6H12O6(aq)
fermentation: C6H12O6(g) --yeast--> 2C2H5OH(aq) + 2CO2(g)
Combustion: C2H5OH(aq) + 3O2(g) --> 2CO2(g) + 3H2O(g)
The amount of CO2 released in fermentation and combustion is equimolar (not sure of this is the right word) to the CO2 absorbed in photosynthesis
However the energy in harvesting, manufacturing, transporting and disposal of the products generally comes from and gives CO2.
In the fermentation process we also only gain 15% ethanol, meaning more energy is used in the process, creating more CO2
Overall ethanol is not a carbon neutral fuel and therefore is not an energy source effective as a countermeasure to climate change. More research is needed in order to to be used as a alternative fuel source which is entirely carbon neutral.

Anyone willing to correct/add to that go ahead :)

Outline the changes that have occured in the atmospheric ozone concentrations above Antarctica during the past 20 years and explain how this information was obtained. - 4 marks
 

Users Who Are Viewing This Thread (Users: 0, Guests: 1)

Top