• Congratulations to the Class of 2024 on your results!
    Let us know how you went here
    Got a question about your uni preferences? Ask us here

Doppler vs pressure broadening? (1 Viewer)

Run hard@thehsc

Well-Known Member
Joined
Oct 7, 2021
Messages
784
Gender
Male
HSC
2022
^^^^ wut the difference between these two when it comes to spectra? Thanks!!!
 

tyrone97

Member
Joined
Sep 10, 2014
Messages
43
Gender
Male
HSC
2014
Doppler broadening is driven by the fact that the source of light is moving towards (blue shifting) or away (red shifting) from the observer. This can be due to random thermal motion or in the context of stellar spectra, the rotation of the source (i.e. if the star is rotating, one half rotates towards the observer, while the other half is rotating away).

Pressure broadening is driven by the fact that atoms colliding with each other cause changes in the energy levels of the electron.
 

Run hard@thehsc

Well-Known Member
Joined
Oct 7, 2021
Messages
784
Gender
Male
HSC
2022
fair - how can we differentiate these two when given a spectra, since both of these result in the thickness of the line spectra increasing? Thanks!
 

tyrone97

Member
Joined
Sep 10, 2014
Messages
43
Gender
Male
HSC
2014
I don't think this it is a meaningful question to ask how the two can be differentiated because in practice, when you look at absorption or emission spectrum it will be broadened due to multiple factors at the same time (i.e. the pressure broadening is layered on top of doppler broadening). You would need to now more about the circumstances in which the spectra were produced to deduce which is more dominant (e.g. high temp low pressure -> doppler broadening, low temp high pressure -> pressure broadening).
 

Run hard@thehsc

Well-Known Member
Joined
Oct 7, 2021
Messages
784
Gender
Male
HSC
2022
I don't think this it is a meaningful question to ask how the two can be differentiated because in practice, when you look at absorption or emission spectrum it will be broadened due to multiple factors at the same time (i.e. the pressure broadening is layered on top of doppler broadening). You would need to now more about the circumstances in which the spectra were produced to deduce which is more dominant (e.g. high temp low pressure -> doppler broadening, low temp high pressure -> pressure broadening).
fair enof that makes sense - suppose we were asked to explain a broadened line spectra, is it still viable if we list both of these as reasons?
 

Users Who Are Viewing This Thread (Users: 0, Guests: 1)

Top